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Linear viscoelastic properties of olefinic thermoplastic elastomer blends: melt state properties

Sengers W. G. F. , Sengupta P. , Noordermeer J. W. M. , Picken Stephen J., Gotsis Alexandros

Πλήρης Εγγραφή


URI: http://purl.tuc.gr/dl/dias/9CE5DE47-44A6-459D-93A0-90AE9A724192
Έτος 2004
Τύπος Δημοσίευση σε Περιοδικό με Κριτές
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Βιβλιογραφική Αναφορά W. G. F. Sengers, P. Sengupta, W. J. M. Noordermeer and A. D. Gotsis, " Linear viscoelastic properties of olefinic thermoplastic elastomer blends: melt state properties", Polymer, vol. 45, no. 26, pp. 8881-8891, Dec. 2004. doi:10.1016/j.polymer.2004.10.030 https://doi.org/10.1016/j.polymer.2004.10.030
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Περίληψη

The linear viscoelastic properties of two types of olefinic thermoplastic elastomer blends were studied using dynamic rheology. The first type consists of a blend of PP, SEBS and oil and has a co-continuous morphology. The second type consists of vulcanised EPDM particles dispersed in a PP matrix. The dynamic rheological behaviour of the blends is a weighted contribution of the properties of the two individual phases. In both blend types, the storage modulus at low frequencies can be correlated to the properties and morphology of the elastomer phase. With increasing PP or oil content in the blend the value of the modulus at low frequencies are reduced. The mechanical models of Coran and Veenstra are able to describe the dynamic moduli. An additional parameter was included to determine the oil concentration in the two phases. The model parameters are correlated to the composition and the morphology.

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