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Effect of Ca substitutions on the properties of YBa2Cu3O6+d

Perdikatsis Vasilis, O. Papageorgiou, M. Calamiotou, G. A. Soifer, Th. Leventouri

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URI: http://purl.tuc.gr/dl/dias/29D9A577-83C3-4CBC-B567-68D344AC2BE7
Year 1994
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation T. Leventouri, G. A. Soifer, M. Calamiotou, O. Papageorgiou, and V. Perdikatsis, "Effect of Ca substitutions on the properties of YBa2Cu3O6+d", Physica C, vol. 235-240, part 1, pp. 375-376, Dec. 1994. doi:10.1016/0921-4534(94)91411-7 https://doi.org/10.1016/0921-4534(94)91411-7
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Summary

We study the effect of Ca substitutions on the structural and superconducting properties of the system of nominal composition YCaFull-size image (<1 K)Ba2−xCu3O6+d. The system remains superconducting up to x=1.00 and the critical temperatures vary between 92 and 80K. A new, non superconducting phase of stoichiometry Y1.14Ca1.58Cu3.27O6.45 appears with concentrations that increase with the nominal concentration of Ca. For x=0.80 and x=1.00 we observe a substitution of the Ba with Ca in crystallites of the form YBa1.8Ca0.2Cu3O6.5.

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