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Technical University of Crete
Technical University of Crete
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| URI | http://purl.tuc.gr/dl/dias/3C05EB97-D000-42B3-BFB7-4E9145522BF9 | - |
| Identifier | http://www.sciencedirect.com/science/article/pii/S0277538713003835 | - |
| Identifier | https://doi.org/10.1016/j.poly.2013.05.016 | - |
| Language | en | - |
| Extent | 6 pages | en |
| Title | Magnetic properties of five planar defect dicubanes of [LnIII4(μ3-OH)2(L)4(HL)2]·2THF (Ln = Gd, Tb, Dy, Ho and Er) | en |
| Creator | Kartik Chandra Mondal | en |
| Creator | Kostakis Georgios | en |
| Creator | Κωστακης Γεωργιος | el |
| Creator | Yanhua Lan | en |
| Creator | Annie K. Powell | en |
| Publisher | Elsevier | en |
| Content Summary | A series of five isostructural tetranuclear defect dicubane, or butterfly, topology 4f coordination clusters of formula [LnIII4(μ3-OH)2(L)4(HL)2]·2THF, [H2L = (E)-2-(2-hydroxy-3-methoxybenzylideneamino)phenol; Ln = Gd(1), Tb(2), Dy(3), Ho(4) and Er(5)) has been synthesized and characterized. The highly anisotropic Dy4 and Ho4 complexes clearly show intramolecular ferromagnetic coupling which arise from dominant intramolecular dipolar–dipolar interactions rather than any significant superexchange effects. Furthermore, the Dy4 complex shows Single Molecule Magnet (SMM) behavior. | en |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-12-03 | - |
| Date of Publication | 2013 | - |
| Subject | Lanthanides | en |
| Subject | Magnetism | en |
| Subject | Single Molecule Magnet | en |
| Subject | Schiff base | en |
| Bibliographic Citation | K. C. Mondal, G. E. Kostakis, Y. Lan, and A. K. Powell, "Magnetic properties of five planar defect dicubanes of [LnIII4(μ3-OH)2(L)4(HL)2]·2THF (Ln = Gd, Tb, Dy, Ho and Er)", Polyhedron, vol. 66, pp. 268-273, Dec. 2013. doi:10.1016/j.poly.2013.05.016 | en |
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