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Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/70C5431B-1F1E-4849-9B15-FB8155DF0ED6 | ||
| Year | 2012 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | G. Abbas, G. E. Kostakis, Y. Lan, and A. K. Powell, "Synthesis and characterization of isostructural tetranuclear lanthanide complexes [Ln4(μ3-OH)2(ampdH4)2(piv)10]·4CH3CN (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er)", Polyhedron, vol. 41, no. 1, pp. 1-6, Jun. 2012. doi:10.1016/j.poly.2012.03.022 https://doi.org/10.1016/j.poly.2012.03.022 | ||
| Appears in Collections |
A series of seven isostructural lanthanide tetramers of general formula [Ln4(μ3-OH)2(ampdH4)2(piv)10] 4CH3CN, where ampdH4 is 3-amino-3-methylpentane-1,5-diol, piv is pivalate, and Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6) and Er (7) have been successfully synthesized and characterized. Magnetic studies on the DyIII analogue show weak intramolecular coupling within the four DyIII ions and Single Molecule Magnet (SMM) behaviour.
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