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Two 3D supramolecular architectures from zinc hydrogen aconitate 1D polymers

Kostakis Georgios, Ebbe Nordlander, Hadjiliadis, Nick, Matti Haukka, Plakatouras, John C

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URI: http://purl.tuc.gr/dl/dias/A320524A-AF0F-43C3-A05E-008EDB20D44F
Year 2006
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation G. E. Kostakis, E. Nordlander, N. Hadjiliadis, M. Haukka, and J. C. Plakatouras, "Two 3D supramolecular architectures from zinc hydrogen aconitate 1D polymers", Inorgan. Chem. Communicat., vol. 9, no. 9, pp. 915-919, Sep. 2006. doi:10.1016/j.inoche.2006.05.031 https://doi.org/10.1016/j.inoche.2006.05.031
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Summary

The reaction of Zn(NO3)2 · 3(H2O) with trans-aconitic acid, in presence of chelating Lewis bases, leads to the formation of the 1D polymers [Zn(N–N)(LH)] · nH2O, where LH3 = trans-aconitic acid, 1 : N–N = 1,10-phenanthroline (phen), n = 1, 2 : N–N = 2,2′-bipyridine (bpy), n = 2. 3D supramolecular assemblies are constructed through H-bonding and stacking interactions.

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