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Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/E6E305EE-6226-4D64-BECD-0B8E10747A2B | ||
| Year | 2012 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | S. Mukherjee, Y. Lan, G. E. Kostakis, R. Clérac, C. E. Anson, and A. K. Powell, "Systematic investigation into the influence of base and substituents on the coordination chemistry of MnIII and MnIII/II salicylate complexes", Supramolecular Chem., vol. 24, no. 8, pp. 533-546, 2012. doi:10.1080/10610278.2012.703323 https://doi.org/10.1080/10610278.2012.703323 | ||
| Appears in Collections |
A systematic investigation into the coordination chemistry of MnIII salicylates is presented revealing the influence on the shape and dimensionality of the final products of base, the presence or absence of co-ligands and the substituents on the salicylates. We report the synthesis, structures, characterisation and magnetic properties of seven compounds, (NHEt3)[MnIII(3-MeOsal)2(MeOH)(H2O)] (1), [NaMnIII(3-MeO-sal)2(MeOH)2] (2), [NaMnIII(sal)2(H2O)(MeOH)] · (MeOH) (3), [KMnIII(sal)2(H2O)(MeOH)] · (MeOH) (4), [MnIIMn2 III(3-MeOsal)4(py)6(H2O)2] · 4H2O, (5), [MnIIMn2 III(3-MeO-sal)4(py)4(H2O)4] · 4MeOH, (6) and [MnIIMn2 III(3-MeO-sal)4(2,2′-bipy)(H2O)3(MeOH)2] · 3MeOH (7). Magnetic studies show the presence of antiferromagnetic interactions between the paramagnetic centres in all cases.
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