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Ternary organic solar cells incorporating zinc phthalocyanine with improved performance exceeding 8.5%

Στυλιανάκης Μηνάς Μ., Viskadouros Georgios, Vernardou Dimitra, Κατσαράκης Νικόλαος, Κουδουμάς Εμμανουήλ, Anastasiadis, Spiros Haralambos, Στρατάκης Εμμανουήλ, Kymakis, Emmanuel, Κωνιός Δημήτριος

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URIhttp://purl.tuc.gr/dl/dias/5F1B6780-F987-460D-B3A6-C79D71C52EF2-
Identifierhttps://www.sciencedirect.com/science/article/pii/S014372081730596X?via%3Dihub-
Identifierhttps://doi.org/10.1016/j.dyepig.2017.07.032-
Languageen-
Extent6 pagesen
TitleTernary organic solar cells incorporating zinc phthalocyanine with improved performance exceeding 8.5%en
CreatorΣτυλιανάκης Μηνάς Μ.el
CreatorStylianakis Minas M.en
CreatorViskadouros Georgiosen
CreatorΒισκαδουρος Γεωργιοςel
CreatorVernardou Dimitraen
CreatorΚατσαράκης Νικόλαοςel
CreatorKatsarakis Nikolaosen
CreatorΚουδουμάς Εμμανουήλel
CreatorKoudoumas Emmanouilen
CreatorAnastasiadis, Spiros Haralambosen
CreatorΣτρατάκης Εμμανουήλel
CreatorStratakis Emmanouelen
CreatorKymakis, Emmanuelen
CreatorΚωνιός Δημήτριοςel
CreatorKonios Dimitriosen
PublisherElsevieren
Content SummaryTernary organic photovoltaic devices have been fabricated, by introducing for the first time, a soluble zinc phthalocyanine (ZnPc) small molecule into the poly-({4,8-bis[(2-thylhexyl)oxy]benzo[1,2-b:4,5-b’]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl] thieno[3,4-b] thiophenediyl}) (PTB7):[6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) active layer. The ZnPc acts as an electron cascade material, providing an efficient energy level offset between the polymeric donor (D) and the fullerene derivative acceptor (A), enhancing charge transfer, reducing exciton recombination and thus improving the photovoltaic performance of the devices. The fabricated ternary organic solar cells of the structure ITO/PEDOT:PSS/PTB7:ZnPc:PC71BM/Ca/Al led to a champion power conversion efficiency (PCE) of 8.52%, increased by ∼15% compared to the reference binary cell. en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2018-03-19-
Date of Publication2017-
SubjectBulk heterojunctionen
SubjectCascade effecten
SubjectCharge transferen
SubjectPhthalocyanineen
SubjectTernary organic solar cellsen
Bibliographic CitationM. M. Stylianakis, D. Konios, G. Viskadouros, D. Vernardou, N. Katsarakis, E. Koudoumas, S. H. Anastasiadis, E. Stratakis and E. Kymakis, "Ternary organic solar cells incorporating zinc phthalocyanine with improved performance exceeding 8.5%," Dyes Pigments, vol. 146, pp. 408-413, Nov., 2017. doi:10.1016/j.dyepig.2017.07.032en

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