X-ray chemical shift determination by energy dispersive detectionX-ray chemical shift determination by energy dispersive detection
Peer-Reviewed Journal Publication
Δημοσίευση σε Περιοδικό με Κριτές
2015-10-101996enX-ray energy shifts due to differences in the chemical states of the emitting elements were investigated. The centroids of the Kα and Kβ characteristic lines produced from chromium and manganese compounds were measured and compared with the centroids of X-ray lines produced from the corresponding metals. Excitation was carried out using a 109Cd radioactive source, and the X-rays were detected with use of a Si(Li) energy dispersive semiconductor detector. solver, a program included in Microsoft Excel for Windows, was used to approximate the form of the X-ray lines with a gaussian function. The results showed that energy dispersive X-ray detection can be used for chemical shift determinations.Δημοσίευση σε επιστημονικό περιοδικό http://creativecommons.org/licenses/by/4.0/Spectrochimica Acta Part B: Atomic Spectroscopy51131655–1659
Kallithrakas-Kontos Nikolaos
Καλλιθρακας-Κοντος Νικολαος
Elsevier
Chemical shifts
Chromium
Energy dispersive X-ray spectrometry
Manganese