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Removal of Per- and polyfluoroalkyl substances (PFAS) from Aqueous Matrices by using Adsorption Processes

Sartzetaki Christina

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URIhttp://purl.tuc.gr/dl/dias/5DF257F8-3C60-4E47-9F88-04817E1D2981-
Identifierhttps://doi.org/10.26233/heallink.tuc.103808-
Languageen-
Extent106 pagesen
TitleRemoval of Per- and polyfluoroalkyl substances (PFAS) from Aqueous Matrices by using Adsorption Processesen
CreatorSartzetaki Christinaen
CreatorΣαρτζετακη Χριστινα Σαρτζετακηel
Contributor [Thesis Supervisor]Xekoukoulotakis Nikosen
Contributor [Thesis Supervisor]Ξεκουκουλωτακης Νικοςel
Contributor [Committee Member]Gournis Dimitriosen
Contributor [Committee Member]Γουρνης Δημητριοςel
Contributor [Committee Member]Diangelakis Nikolaosen
Contributor [Committee Member]Διαγγελακης Νικολαοςel
PublisherΠολυτεχνείο Κρήτηςel
PublisherTechnical University of Creteen
Academic UnitTechnical University of Crete::School of Chemical and Environmental Engineeringen
Academic UnitΠολυτεχνείο Κρήτης::Σχολή Χημικών Μηχανικών και Μηχανικών Περιβάλλοντοςel
DescriptionPostgraduate thesis submitted to the faculty of Chemical and Environmental Engineering of the Technical University of Creteen
Content SummaryPer- and polyfluoroalkyl substances (PFAS) are persistent organic pollutants that have been detected in various aqueous environments. Due to their chemical stability and health risks, effective removal technologies are urgently needed. Among emerging sorbents, β-cyclodextrin (β-CD) polymers have attracted interest for their tunable selectivity and environmental compatibility. This thesis investigates the adsorption behavior of per- and polyfluoroalkyl substances (PFAS) onto β-cyclodextrin (β-CD)-based polymers, with a focus on how surface functionalization and polymer architecture influence removal efficiency. Five case studies and one meta-analysis were analyzed to explore key performance trends across different material chemistries, PFAS types, and water matrices. The results indicate that unmodified β-CD polymers show limited effectiveness, particularly for short-chain PFAS, while functionalized variants—especially those incorporating cationic groups—demonstrate high selectivity and fast kinetics even under complex environmental conditions. The study highlights the importance of electrostatic interactions, host–guest inclusion, and steric factors in driving adsorption performance. Finally, key challenges related to material scalability, integration into treatment systems, and regulatory pathways are discussed, outlining promising directions for future research and application.en
Type of ItemΜεταπτυχιακή Διατριβήel
Type of ItemMaster Thesisen
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2025-07-11-
Date of Publication2025-
SubjectAdsorption technology el
Bibliographic CitationChristina Sartzetaki, "Removal of Per- and polyfluoroalkyl substances (PFAS) from Aqueous Matrices by using Adsorption Processes", Master Thesis, School of Chemical and Environmental Engineering, Technical University of Crete, Chania, Greece, 2025en

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