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Dissolution of a multicomponent DNAPL pool in an experimental aquifer

Chrysikopoulos Constantinos, Kenneth Y. Lee

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URI: http://purl.tuc.gr/dl/dias/6997D60A-8495-4795-9EEF-C52EF7C3C966
Year 2006
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation K. Y. Lee , C. V. Chrysikopoulos , " Dissolution of a multicomponent DNAPL pool in an experimental aquifer ",Jour. of Haza.Mater., pp 218–226.,2006, doi:10.1016/j.jhazmat.2005.08.005. https://doi.org/10.1016/j.jhazmat.2005.08.005
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Summary

This paper presents the results from a well-defined, circular-shaped, multicomponent dense nonaqueous phase liquid (DNAPL) pool dissolutionexperiment conducted in a three-dimensional, bench scale model aquifer. The multicomponent pool is a mixture of tetrachloroethylene(PCE) and 1,1,2-trichloroethane (1,1,2-TCA); PCE was the major component and 1,1,2-TCA was the minor component. Downgradient plumeconcentrations were measured at five specific locations over time until the majority of the 1,1,2-TCA was depleted from the DNAPL poolsource. The experimental results suggest distinct spatial-temporal plume patterns for minor DNAPL components versus major DNAPL components.The downgradient concentration varied over time for 1,1,2-TCA while a stable plume developed for PCE. A semi-analytical solutionfor contaminant transport resulting from dissolution of multicomponent nonaqueous phase liquid pools successfully simulated the plumestructure and dynamics for both the major and minor DNAPL components.© 2005 Elsevier B.V. All rights reserved.

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