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Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/EF6B6050-2017-4952-B1CA-B6A1D3D97B8C | ||
| Year | 1998 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | J. S Fleming, K. LV Mann, C.A.Carraz, E.Psillakis, J. C Jeffery, J. A McCleverty, M.D Ward , "Anion-Templated Assembly of a Supramolecular Cage Complex ",Ang. chem. interna. edit.,vol.37,no.9 ,pp.1279-1281,1998.doi:10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q https://doi.org/10.1002/(SICI)1521-3773(19980518)37:9<1279::AID-ANIE1279>3.0.CO;2-Q | ||
| Appears in Collections |
THe templating effect of the tetrafluoroborate ion leads to assembly of four CoII ions and six bridging ligands around this anion to give a tetrahedral complex with a bridging ligand along each edge and the anion trapped in the central cavity (shown below). Surprisingly under identical conditions but with NiII a simpler dinuclear complex forms.
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