Institutional Repository
Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/E9BDD35A-9831-42EE-A8AF-C163C729E75F | ||
| Year | 1998 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | C. A Otter, S. M Couchman, J. C Jeffery, K. LV Mann, E. Psillakis, M.D Ward , "Complexes of a new bidentate chelating pyridyl/sulfonamide ligand with copper(II), cobalt(II) and palladium(II): crystal structures and spectroscopic properties ", Inor.a chimica acta , vol. 278, no. 2, pp. 178–184 ,1998.doi:10.1016/S0020-1693(98)00018-8 https://doi.org/10.1016/S0020-1693(98)00018-8 | ||
| Appears in Collections |
Reaction of the bidentate ligand 2-(2-aminophenyl)pyridine with p-toluenesulfonyl chloride afforded the new bidentate ligand HL which contains potentially chelating pyridyl and (protonated) sulfonamide N-donor binding sites. The crystal structure of the ligand shows that the sulfonamide NH proton is involved in a hydrogen-bonding interaction with the pyridyl N atom, resulting in a near-coplanar arrangement of the pyridyl and phenyl rings.
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