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Technical University of Crete
Technical University of Crete
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| URI | http://purl.tuc.gr/dl/dias/A71FF72D-711A-4221-8DEB-819568FAECC6 | - |
| Identifier | https://doi.org/10.1039/A606827H | - |
| Language | en | - |
| Extent | 1 PAGES | en |
| Title | Copper(II)-templated assembly of tetranuclear grid-like complexesfrom simple pyridine–pyrazole ligands | en |
| Creator | Elefteria Psillakis | en |
| Creator | Karen LV Mann | en |
| Creator | Jon A McCleverty | en |
| Creator | Claire M White | en |
| Publisher | Royal Society of Chemistry | en |
| Content Summary | Reaction of Cu(O 2 CMe) 2 ·H 2 O with HL 1 [3-(2-pyridyl)pyrazole] or HL 2 [6-(3-pyrazolyl)-2,2′-bipyridine] and NH 4 PF 6 followed by crystallisation of the crude products from dmf–ether affords [Cu 4 L 1 6 (dmf) 2 ][PF 6 ] 2 1 and [Cu 4 L 2 4 (dmf) 4 ]- [PF 6 ] 4 2 respectively, in which the deprotonated pyrazolyl groups act as bridging ligands and the 2 × 2 grid–like architectures are a result of the preference of the Cu II ions for elongated square-pyramidal coordination geometries. | en |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-09-24 | - |
| Date of Publication | 1997 | - |
| Bibliographic Citation | J. C Jeffery, P.L Jones, K. LV Mann, E. Psillakis, J. A McCleverty, M. D Ward, C. M White , "Copper(II)-templated assembly of tetranuclear grid-like complexesfrom simple pyridine–pyrazole ligands ",Ch.Communicat.,vol. 2 ,pp.175-176,1997.doi : 10.1039/A606827H | el |
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