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A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes

Psyllaki Eleftheria, Bardwell David A., Crossle John G., Orpen, A. Guy, Jeffer John C., Tilley Elizabeth E. M.

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URIhttp://purl.tuc.gr/dl/dias/3A4CD4A2-AB91-4C03-BF1C-DA572E3EAD21-
Αναγνωριστικόhttps://doi.org/10.1016/S0277-5387(00)88139-5-
Αναγνωριστικόhttps://www.sciencedirect.com/science/article/pii/S0277538700881395-
Γλώσσαen-
Μέγεθος10 pagesel
ΤίτλοςA study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexesen
ΔημιουργόςPsyllaki Eleftheriaen
ΔημιουργόςΨυλλακη Ελευθεριαel
ΔημιουργόςBardwell David A.en
ΔημιουργόςCrossle John G.en
ΔημιουργόςOrpen, A. Guyen
ΔημιουργόςJeffer John C.en
ΔημιουργόςTilley Elizabeth E. M.en
ΕκδότηςPergamonen
ΠερίληψηThe crystal structures of the series of four-coordinate complexes [PdL1Cl) · CH2Cl2 (1·CH2Cl2), [PtL1Cl]·CH2Cl2 (2·CH2Cl2), [PdL3Cl][PF6 · CH2Cl2 (3 · CH2Cl2) and [PdL4Cl][PF6 (4) [HL1 = 6-(2-hydroxyphenyl)-2,2′-bipyridine; L3 = 6-(2-dimethylaminophenyl)-2,2′-bipyridine; L4 = 2-(2-dimethylaminophenyl)-1,10-phenanthroline] are compared and contrasted to examine the extent to which aromatic π-stacking interactions contribute to crystal packing. Complexes 1 and 2 have very similar planar molecular structures but stack in different ways; molecules of 1 form a linear stack in which overlap of the aromatic ligands is maximized between adjacent molecules and there is no PdPd interaction, whereas in 2 there are axial PtPt interactions within the linear stack but less overlap between adjacent aromatic ligands.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-09-24-
Ημερομηνία Δημοσίευσης1994-
Θεματική ΚατηγορίαCrystal packingen
Βιβλιογραφική ΑναφοράD. A. Bardwell, J. G. Crossley, J. C. Jeffery, A. G. Orpen, E. Psillakis, E. E. Tilley, M. D Ward, "A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes, " Polyhendron, vol. 13, no. 15–16, pp. 2291–2300, Aug. 1994. doi: 10.1016/S0277-5387(00)88139-5en

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