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Technical University of Crete
Technical University of Crete
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| URI | http://purl.tuc.gr/dl/dias/BACF5449-143C-438E-B2AF-813C55CEE3E5 | - |
| Identifier | https://doi.org/10.1016/S0022-328X(98)00363-5 | - |
| Language | en | - |
| Extent | 10 pages | en |
| Title | Synthesis, crystal structure and some reactions of the ruthenacarborane complex [Ru(CO)2(MeC,CPh)(η5-7,8-C2B9H11]. | el |
| Creator | Elefteria Psillakis | en |
| Creator | John C Jeffery | en |
| Creator | Paul A Jelliss | en |
| Creator | Gillian EA Rudd | en |
| Creator | F Gordon A Stone | en |
| Publisher | Elsevier | en |
| Content Summary | The alkyne complex [Ru(CO) 2 (MeC,CPh)(η 5 -7,8-C 2 B 9 H 11 ] (3c) has been prepared and its structure determined by X-ray crystallography. The ruthenium is co-ordinated on one side by the nido-7,8-C 2 B 9 H 11 fragment in a pentahapto manner, and on the other by the two CO molecules and the alkyne [Ru–C av. =2.305, C–C=1.228(3) Å. Treatment of 3c with PEt 3 and Ph 2 PCH 2 PPh 2 in CH 2 Cl 2 affords the ylid complexes [Ru{C(Me)C(Ph)PEt 3 }(CO) 2 (η 5 -7,8-C 2 B 9 H 11 )] (4b) and [Ru{C(Me)C(Ph)P(Ph) 2 CH 2 PPh 2 }(CO) 2 (η 5 -7,8-C 2 B 9 H 11 )] (4c), respectively. The structure of 4b was established by an X-ray diffraction study which revealed that the PEt 3 molecule was attached to the carbon atom of the CPh group. In contrast, reactions between 3c and the donor molecules AsPh 3 , SbPh 3 and Ph 2 P(S)CH 2 P(S)Ph 2 resulted in displacement of the alkyne and formation of the complexes [Ru(CO) 2 (L)(η 5 -7,8-C 2 B 9 H 11 )] (5a, L=AsPh 3 ; 5b, L=SbPh 3 ; 5c, L=Ph 2 P(S)CH 2 P(S)Ph 2 ). Treatment of 4c with the Ru(CO) 2 (η 5 -7,8-C 2 B 9 H 11 ) fragment yielded the diruthenium complex [Ru 2 (μ-Ph 2 PCH 2 PPh 2 )(CO) 4 (η 5 -7,8-C 2 B 9 H 11 ) 2 ] (6). The structure, based on the linking of two Ru(CO) 2 (η 5 -7,8-C 2 B 9 H 11 ) groups by the ligand Ph 2 PCH 2 PPh 2 , was determined by X-ray crystallography. NMR data for the new complexes are reported. | el |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-09-24 | - |
| Date of Publication | 1998 | - |
| Bibliographic Citation | J.C Jeffery, P. A Jelliss, E.Psillakis, G. EA Rudd, F G. A Stone, "Synthesis, crystal structure and some reactions of the ruthenacarborane complex [Ru(CO)2(MeC,CPh)(η5-7,8-C2B9H11] ",J. of organ. chem.,vol. 562,no.1,pp.17-27,1998.doi:10.1016/S0022-328X(98)00363-5 | el |
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