URI | http://purl.tuc.gr/dl/dias/F771EC85-D245-4487-8B4F-E24D15ED6D05 | - |
Αναγνωριστικό | https://doi.org/ 10.1039/A703643D | - |
Γλώσσα | en | - |
Μέγεθος | 2 pages | en |
Τίτλος | Square-prismatic vs. square-antiprismatic coordination in complexes of lead(II) with a simple bidentate chelating ligand; effects of intermolecular hydrogen bonding | en |
Δημιουργός | Elefteria Psillakis | en |
Δημιουργός | JohnáC Jeffery | en |
Εκδότης | Royal Society of Chemistry | en |
Περίληψη | Whereas the eight-coordinate complex cation of [PbL4][(MeO)2PO2]·2H2O [L = 3-(2-pyridyl)pyrazole] has square prismatic geometry stabilised by hydrogen bonding between the pyrazolyl NH groups and the dimethylphosphate anion, the complex cation of [PbL4][PF6]2, in which there are no significant hydrogen-bonding interactions, has a structure distorted towards square antiprismatic with a 22° twist between the planes. | en |
Τύπος | Peer-Reviewed Journal Publication | en |
Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | el |
Άδεια Χρήσης | http://creativecommons.org/licenses/by/4.0/ | en |
Ημερομηνία | 2015-09-25 | - |
Ημερομηνία Δημοσίευσης | 1997 | - |
Βιβλιογραφική Αναφορά | E. Psillakis , J. C. Jeffery ,"Square-prismatic vs. square-antiprismatic coordination in complexes of lead(II) with a simple bidentate chelating ligand; effects of intermolecular hydrogen bonding ",Chem. Commun., vol.20 ,pp. 1965-1966,1997.doi: 10.1039/A703643D | en |