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Origin and mobility of hexavalent chromium in North-Eastern Attica, Greece

Moraitis Daniil, Nikolaidis Nikolaos, Karatzas Giorgos, Dokou Zoi, Kalogerakis Nikos, Winkel L.H.E. , Παλαιογιάννη-Μπέλλου Άρτεμις

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/6D9FDD73-6DE1-47C5-91D3-1816BDD0198B-
Αναγνωριστικόhttps://doi.org/10.1016/j.apgeochem.2012.03.005-
Αναγνωριστικόhttps://www.sciencedirect.com/science/article/pii/S0883292712000819-
Γλώσσαen-
Μέγεθος9 pagesel
ΤίτλοςOrigin and mobility of hexavalent chromium in North-Eastern Attica, Greeceen
ΔημιουργόςMoraitis Daniilen
ΔημιουργόςΜωραϊτης Δανιηλel
ΔημιουργόςNikolaidis Nikolaosen
ΔημιουργόςΝικολαιδης Νικολαοςel
ΔημιουργόςKaratzas Giorgosen
ΔημιουργόςΚαρατζας Γιωργοςel
ΔημιουργόςDokou Zoien
ΔημιουργόςΔοκου Ζωηel
ΔημιουργόςKalogerakis Nikosen
ΔημιουργόςΚαλογερακης Νικοςel
ΔημιουργόςWinkel L.H.E. en
ΔημιουργόςΠαλαιογιάννη-Μπέλλου Άρτεμιςel
ΔημιουργόςPalaiogianni-Bellou Artemisen
ΕκδότηςElsevieren
ΠεριγραφήΔημοσίευση σε επιστημονικό περιοδικό el
ΠερίληψηAn integrated framework that is comprised of field surveys of groundwater, surface water and soils, laboratory process experiments and hydrologic and geochemical modeling is used to identify the origin (anthropogenic versus geogenic sources), fate and transport of hexavalent Cr in Tertiary and Quaternary deposits of Oropos plain in Greece. Groundwater and soils were analyzed in May 2008 and exhibited considerable Cr concentrations. Mineralogical analysis and micro-XRF analysis of the heavy soil fractions (metallic components) showed Cr bearing phases like chromites, Cr-silicate phases with positive correlation between Si, Al, Fe and Cr soil concentrations. Column experiments showed the Cr(VI) desorption ability of soils, e.g. concentration of 20 μg L−1 was detected after the application of 50 mm of rain. The groundwater model simulated the variability of Cr concentrations emanating from both anthropogenic and geogenic sources, successfully using rate constants obtained from the laboratory experiments, e.g. 4.24 nM h−1 for serpentine soil and 0.77 nM h−1 for soil in alluvial deposits. The mineralogical and geochemical results support a geogenic origin for Cr in soils and groundwater of Oropos plain while modeling results suggest that contaminants transported by Asopos River have affected only the upper layers of the subsurface in the vicinity of the river. The framework can be used to establish background concentrations or clean up levels of Cr-contaminated soils and groundwater.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-10-12-
Ημερομηνία Δημοσίευσης2012-
Θεματική ΚατηγορίαIntegrated framework en
Θεματική Κατηγορία Oropos plainen
Θεματική ΚατηγορίαGroundwateren
Βιβλιογραφική ΑναφοράD. Moraetis, N.P. Nikolaidis, G.P. Karatzas, Z. Dokou, N. Kalogerakis, L.H.E. Winkelb and A. Palaiogianni-Bellou, "Origin and mobility of hexavalent chromium in North-Eastern Attica, Greece," Appl. Geochem., vol. 27, no. 6, pp. 1170–1178, Jun. 2012. doi: 10.1016/j.apgeochem.2012.03.005el

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