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Boron-doped diamond anodic treatment of olive mill wastewaters: statistical analysis, kinetic modeling and biodegradability

Xekoukoulotakis Nikos, Mantzavinos Dionysis, Diamantopoulos Evaggelos, Katsaounis Alexandros, Chatzisymeon Efthalia

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/19C770EF-84C4-4644-877F-755D85BDE770-
Αναγνωριστικόhttps://doi.org/http://www.sciencedirect.com/science/article/pii/S004313540900236X-
Αναγνωριστικόhttps://doi.org/10.1016/j.watres.2009.04.007-
Γλώσσαen-
Μέγεθος10 pagesen
ΤίτλοςBoron-doped diamond anodic treatment of olive mill wastewaters: statistical analysis, kinetic modeling and biodegradabilityen
ΔημιουργόςXekoukoulotakis Nikosen
ΔημιουργόςΞεκουκουλωτακης Νικοςel
ΔημιουργόςMantzavinos Dionysisen
ΔημιουργόςΜαντζαβινος Διονυσηςel
ΔημιουργόςDiamantopoulos Evaggelosen
ΔημιουργόςΔιαμαντοπουλος Ευαγγελοςel
ΔημιουργόςKatsaounis Alexandrosen
ΔημιουργόςΚατσαουνης Αλεξανδροςel
ΔημιουργόςChatzisymeon Efthaliaen
ΔημιουργόςΧατζησυμεων Ευθαλιαel
ΕκδότηςElsevieren
ΠερίληψηThe electrochemical treatment of olive mill wastewaters (OMW) over boron-doped diamond (BDD) electrodes was investigated. A factorial design methodology was implemented to evaluate the statistically important operating parameters, amongst initial COD load (1000–5000 mg/L), treatment time (1–4 h), current intensity (10–20 A), initial pH (4–6) and the use of 500 mg/L H2O2 as an additional oxidant, on treatment efficiency; the latter was assessed in terms of COD, phenols, aromatics and color removal. Of the five parameters tested, the first two had a considerable effect on COD removal. Hence, analysis was repeated at more intense conditions, i.e. initial COD values up to 10,000 mg/L and reaction times up to 7 h and a simple model was developed and validated to predict COD evolution profiles. The model suggests that the rate of COD degradation is zero order regarding its concentration and agrees well with an electrochemical model for the anodic oxidation of organics over BDD developed elsewhere. The treatability of the undiluted effluent (40,000 mg/L COD) was tested at 20 A for 15 h yielding 19% COD and 36% phenols' removal respectively with a specific energy consumption of 96 kW h/kg COD removed. Aerobic biodegradability and ecotoxicity assays were also performed to assess the respective effects of electrochemical treatment.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-10-22-
Ημερομηνία Δημοσίευσης2009-
Θεματική ΚατηγορίαBoron-doped diamonden
Θεματική ΚατηγορίαElectrolysisen
Θεματική ΚατηγορίαFactorial designen
Θεματική ΚατηγορίαOlive mill wastewateren
Θεματική ΚατηγορίαBiodegradabilityen
Βιβλιογραφική ΑναφοράE. Chatzisymeon, N. P. Xekoukoulotakis, E. Diamadopoulos, A. Katsaounis and D. Mantzavinos, "Βoron-doped diamond anodic treatment of olive mill wastewaters: statistical analysis, kinetic modelling and biodegradability," Water Res., vol. 43, no. 16, pp. 3999-4009, Sep. 2009. doi.org/10.1016/j.watres.2009.04.007. en

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