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Arsenic mobility in contaminated lake sediments

Nikolaidis Nikolaos, Gregory M Dobbs, Jing Chen, Jeffrey A Lackovic

Πλήρης Εγγραφή


URI: http://purl.tuc.gr/dl/dias/DDADA291-4F38-4171-BE71-4FB9B0499F92
Έτος 2004
Τύπος Δημοσίευση σε Περιοδικό με Κριτές
Άδεια Χρήσης
Λεπτομέρειες
Βιβλιογραφική Αναφορά Nikolaidis, N.P., G.M. Dobbs, and J.A. Lackovic, "Arsenic Mobility in Contaminated Lake Sediment", Environmental Pollution, Vol. 129, no. 3, pp. 479-487, Jul. 2004. DOI: 10.1016/j.envpol.2003.11.005 https://doi.org/10.1016/j.envpol.2003.11.005
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Περίληψη

An arsenic contaminated lake sediment near a landfill in Maine was used to characterize the geochemistry of arsenic and assess the influence of environmental conditions on its mobility. A kinetic model was developed to simulate the leaching ability of arsenic in lake sediments under different environmental conditions. The HM1D chemical transport model was used to model the column experiments and determine the rates of arsenic mobility from the sediment. Laboratory studies provided the information to construct a conceptual model to demonstrate the mobility of arsenic in the lake sediment. The leaching ability of arsenic in lake sediments greatly depends on the flow conditions of ground water and the geochemistry of the sediments. Large amounts of arsenic were tightly bound to the sediments. The amount of arsenic leaching out of the sediment to the water column was substantially decreased due to iron/arsenic co-precipitation at the water-sediment interface. Overall, it was found that arsenic greatly accumulated at the ground water/lake interface and it formed insoluble precipitates.

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