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Low temperature steam reforming of ethanol over supported noble metal catalysts

Panagiotopoulou Paraskevi, Xenophon E. Verykios, Aristides C. Basagiannis

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/E5D9E577-5438-4390-BD68-D565C1002EC7-
Αναγνωριστικόhttps://doi.org/10.1007/s11244-008-9130-z-
Γλώσσαen-
Μέγεθοςpages 2-12en
ΤίτλοςLow temperature steam reforming of ethanol over supported noble metal catalystsen
ΔημιουργόςPanagiotopoulou Paraskevien
ΔημιουργόςΠαναγιωτοπουλου Παρασκευηel
ΔημιουργόςXenophon E. Verykiosen
ΔημιουργόςAristides C. Basagiannisen
ΕκδότηςSpringer Linken
Περίληψηhe catalytic activity of M/Al2O3 catalysts for the reaction of steam reforming of ethanol has been investigated in the temperature range of 300–450 °C. It has been found that the catalytic performance varies in the order of Pt > Pd > Rh > Ru, with Pt exhibiting high activity and selectivity toward hydrogen production, as well as long term stability at low temperatures. It is shown that the reaction occurs in a bifunctional manner, with the participation of both the dispersed metallic phase and the support. Ethanol interacts strongly with the Al2O3 carrier, promoting mainly ethanol dehydration, while in the presence of Pt, catalytic activity is shifted toward lower temperatures. Ethanol decomposition and dehydrogenation reactions dominate at low temperatures, while reforming, water-gas shift and methanation contribute significantly to product distribution.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-10-23-
Ημερομηνία Δημοσίευσης2008-
Βιβλιογραφική ΑναφοράA.C. Basagiannis, P. Panagiotopoulou, X.E. Verykios, “Low temperature steam reforming of ethanol over supported noble metal catalysts”, Topics in Catalysis,Vol. 51, no. 1, pp. 2-12, Dec. 2008. doi:10.1007/s11244-008-9130-z.en

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