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Oxidative coupling of methane to C2 hydrocarbons over titania-based catalysts

Papageorgiou, Demetris, Vamvouka Despoina, Boudouvas D. , Verykios, Xenophon E

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URIhttp://purl.tuc.gr/dl/dias/42FF7E27-6BBF-4492-8428-0C3E8BD78AA2-
Identifierhttp://www.sciencedirect.com/science/article/pii/092058619280164I-
Identifierhttps://doi.org/10.1016/0920-5861(92)80164-I-
Languageen-
Extent10 pagesen
TitleOxidative coupling of methane to C2 hydrocarbons over titania-based catalystsen
CreatorPapageorgiou, Demetrisen
CreatorVamvouka Despoinaen
CreatorΒαμβουκα Δεσποιναel
CreatorBoudouvas D. en
CreatorVerykios, Xenophon Een
PublisherElsevieren
Content SummaryThe influence of altervalent doping of TiO2 on its activity and selectivity under methane oxidative coupling conditions is investigated. It is found that doping TiO2 with cations of valence lower than that of the parent cation (Li+, Zn+2) results in reduction of catalytic activity and enhancement of selectivity towards C2 hydrocarbons formation. The opposite is observed upon doping TiO2 with higher valence cations (Nb+5, Ta+5, W6+). Hydrocarbon yields as high as 28% are observed over 1% Li2O-doped TiO2 at 800°C.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-10-26-
Date of Publication1992-
SubjectMethaneen
Bibliographic CitationD. Papageorgiou, D. Vamvouka, D. Boudouvas and X.E. Verykios, "Oxidative coupling of methane to C2 hydrocarbons over titania- based catalysts", Catal. Today, vol. 13, no. 1-2, pp. 391-400, Mar. 1992. doi:10.1016/0920-5861(92)80164-Ien

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