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Optimization of the HPLC separation of aromatic groups in petroleum fractions

Pasadakis Nikos, Varotsis Nikolaos

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URIhttp://purl.tuc.gr/dl/dias/AF940269-EAEE-4EE4-8F55-5F299C9DC12E-
Identifierhttp://www.sciencedirect.com/science/article/pii/S0016236199002884-
Identifierhttps://doi.org/10.1016/S0016-2361(99)00288-4-
Languageen-
Extent5 pagesen
TitleOptimization of the HPLC separation of aromatic groups in petroleum fractionsen
CreatorPasadakis Nikosen
CreatorΠασαδακης Νικοςel
CreatorVarotsis Nikolaosen
CreatorΒαροτσης Νικολαοςel
PublisherElsevieren
Content SummaryAn experimental procedure was developed for improving the separation between the aromatic component groups in petroleum fractions by high performance liquid chromatography. The mobile phase composition, consisting of n-hexane, chloroform and isopropyl ether was optimized with respect to the resolution between the aromatic component groups and the analysis time. The overlapping resolution mapping scheme was used for the establishment of the optimum mobile phase composition. A solvent composition (95% n-hexane–5% isopropyl ether) was found to provide the best resolution of the aromatic components while the required analysis time is kept reasonably low (30 min). The method was subsequently applied to the analysis of gas oil samples and demonstrated better separation profile of the aromatic groups in comparison with experimental results previously reported.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-10-27-
Date of Publication2000-
SubjectPetroleum fractionen
SubjectHigh performance chromatographyen
SubjectHigh pressure liquid chromatographyen
SubjectHigh sensitivity liquid chromatographyen
SubjectHigh speed liquid chromatographyen
SubjectHPLC (Chromatography)en
Subjecthigh performance liquid chromatographyen
Subjecthigh performance chromatographyen
Subjecthigh pressure liquid chromatographyen
Subjecthigh sensitivity liquid chromatographyen
Subjecthigh speed liquid chromatographyen
Subjecthplc chromatographyen
SubjectAromaticsen
Bibliographic CitationN. Pasadakis and N. Varotsis, "Optimization of the HPLC separation of aromatic groups in petroleum fractions", Fuel, vol. 79, no. 12, pp. 1455-1459, Oct. 2000. doi:10.1016/S0016-2361(99)00288-4en

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