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Ion spillover as the origin of NEMCA effect

Vayenas, Costas G, Bebelis, Symeon, Gentekakis Ioannis, Neophytides, S. G, Jiang Yi

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URIhttp://purl.tuc.gr/dl/dias/2B2A4E7A-0590-4119-AD79-25DF4EC9E12E-
Identifierhttp://www.sciencedirect.com/science/article/pii/S0167299108631614-
Identifierhttps://doi.org/10.1016/S0167-2991(08)63161-4-
Languageen-
Extent6 pagesen
TitleIon spillover as the origin of NEMCA effecten
CreatorVayenas, Costas Gen
CreatorBebelis, Symeonen
CreatorGentekakis Ioannisen
CreatorΓεντεκακης Ιωαννηςel
CreatorNeophytides, S. Gen
CreatorJiang Yien
PublisherElsevieren
Content SummaryThe catalytic activity and selectivity of metal films deposited on solid electrolytes can be altered dramatically and reversibly via the effect of Non-Faradaic Electrochemical Modification of Catalytic Activity (NEMCA). In the present paper we briefly summarize the main features of the NEMCA effect and present and discuss the existing kinetic, electrokinetic and surface spectroscopic evidence that NEMCA is due to an electrochemically induced and controlled ion spillover from/to the solid electrolyte to/from the metal catalyst surface.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-10-30-
Date of Publication1993-
SubjectCatalysisen
Bibliographic CitationC. G. Vayenas, S. Bebelis, I. V. Yentekakis, S. Neophytides and J. Yi, "Ion spillover as the origin of NEMCA effect", Stud. Surf. Sci. Catal., vol. 77, pp. 111-116, Jan. 1993. doi:10.1016/S0167-2991(08)63161-4en

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