Ιδρυματικό Αποθετήριο
Πολυτεχνείο Κρήτης
Πολυτεχνείο Κρήτης
EN
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EL
| URI: | http://purl.tuc.gr/dl/dias/894DAE05-23FF-4AAC-A6A1-F2B44EF3FC56 | ||
| Έτος | 1997 | ||
| Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | ||
| Άδεια Χρήσης |
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| Βιβλιογραφική Αναφορά | I. V. Yentekakis, Y. Jiang, M. Makri and C. G. Vayenas, "Oxidative coupling of methane to ethylene with 85% yield in a gas recycle electrocatalytic or catalytic reactor separator", Stud. Surf. Sci. Catal., vol. 107, pp. 307-312, 1997. doi:10.1016/S0167-2991(97)80352-7 https://doi.org/10.1016/S0167-2991(97)80352-7 | ||
| Εμφανίζεται στις Συλλογές |
A novel gas-recycle electrocatalytic or catalytic reactor-separator has been developed which gives very high ethylene yields during the oxidative coupling of methane. The recycled gas passes continuously through a molecular sieve trap in the recycle loop, which traps and thus protects an easily controllable percentage (up to 100%) of C2H4 and C2H6 produced during each gas cycle. The C2 products are obtained by subsequent heating of the molecular sieve trap. Ethylene yields up to 85% (88% C2H4 selectivity at 97% methane conversion) were achieved during batch operation while ethylene yields up to 50% (65% C2H4 selectivity at 76% methane conversion) were obtained during continuous-flow, steady-state operation.
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