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Steady – state homogeneous nucleation of the sulfuric acid – water system

Lazaridis Michalis

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URIhttp://purl.tuc.gr/dl/dias/31DDBC26-50AF-4DC6-B7B9-728FB644B05D-
Αναγνωριστικόhttps://doi.org/10.1016/S0009-2614(98)01094-X-
Γλώσσαen-
Μέγεθος6 pagesen
ΤίτλοςSteady – state homogeneous nucleation of the sulfuric acid – water systemen
ΔημιουργόςLazaridis Michalisen
ΔημιουργόςΛαζαριδης Μιχαληςel
ΕκδότηςElsevieren
ΠερίληψηHomogeneous nucleation of highly non-ideal liquid solutions is examined using an analytical method to obtain the steady-state nucleation flux. The theory is applied to the water–sulfuric acid binary system. The method for obtaining the nucleation flux is based on the solution of a Fokker–Planck equation for the concentration of clusters where both number (size) and cluster-energy fluctuations are included. The Fokker–Planck equation is solved in the vicinity of the saddle point. The kinetic prefactor is found to depend on the product of the three eigenvalues of a matrix that describes fluctuations about the critical cluster. Contrary to more ideal binary systems (such as the ethanol–water system), the model predicts considerable higher nucleation rates compared to the classical nucleation theory.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-11-10-
Ημερομηνία Δημοσίευσης1998-
Θεματική ΚατηγορίαHomogeneous nucleationen
Βιβλιογραφική ΑναφοράM. Lazaridis “Steady – state homogeneous nucleation of the sulfuric acid – water system, '' Ch.Physics Letters ,vol.296,no.5-6, pp. 477-482 , Nov. 1998.doi: 10.1016/S0009-2614(98)01094-Xen

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