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Development of a modified independent parallel reactions kinetic model and comparison with the distributed activation energy model for the pyrolysis of a wide variety of biomass fuels

Vamvouka Despoina, Sfakiotakis Stylianos

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/58C9E41A-08E2-445A-B870-55ABBE5D78D6-
Αναγνωριστικόhttp://www.sciencedirect.com/science/article/pii/S0960852415012365-
Αναγνωριστικόhttps://doi.org/10.1016/j.biortech.2015.08.130-
Γλώσσαen-
Μέγεθος9 pagesen
ΤίτλοςDevelopment of a modified independent parallel reactions kinetic model and comparison with the distributed activation energy model for the pyrolysis of a wide variety of biomass fuelsen
ΔημιουργόςVamvouka Despoinaen
ΔημιουργόςΒαμβουκα Δεσποιναel
ΔημιουργόςSfakiotakis Stylianosen
ΔημιουργόςΣφακιωτακης Στυλιανοςel
ΕκδότηςElsevieren
ΠερίληψηThe pyrolysis of six waste biomass samples was studied and the fuels were kinetically evaluated. A modified independent parallel reactions scheme (IPR) and a distributed activation energy model (DAEM) were developed and their validity was assessed and compared by checking their accuracy of fitting the experimental results, as well as their prediction capability in different experimental conditions. The pyrolysis experiments were carried out in a thermogravimetric analyzer and a fitting procedure, based on least squares minimization, was performed simultaneously at different experimental conditions. A modification of the IPR model, considering dependence of the pre-exponential factor on heating rate, was proved to give better fit results for the same number of tuned kinetic parameters, comparing to the known IPR model and very good prediction results for stepwise experiments. Fit of calculated data to the experimental ones using the developed DAEM model was also proved to be very good.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2015-11-15-
Ημερομηνία Δημοσίευσης2015-
Θεματική ΚατηγορίαPyrolysis kineticsen
Θεματική ΚατηγορίαIPR modelen
Θεματική ΚατηγορίαDAEM modelen
Θεματική ΚατηγορίαWoody residuesen
Θεματική ΚατηγορίαWaste biomassen
Βιβλιογραφική ΑναφοράS. Sfakiotakis, and D. Vamvuka, "Development of a modified independent parallel reactions kinetic model and comparison with the distributed activation energy model for the pyrolysis of a wide variety of biomass fuels", Biores. Technol., vol. 197, pp. 434-442, Dec. 2015. doi:10.1016/j.biortech.2015.08.130en

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