Institutional Repository
Technical University of Crete
Technical University of Crete
EN
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EL
| URI | http://purl.tuc.gr/dl/dias/4125E0F3-419C-4429-9CC8-ADEC7B2E4776 | - |
| Identifier | http://www.sciencedirect.com/science/article/pii/S0167273806002001 | - |
| Identifier | https://doi.org/10.1016/j.ssi.2006.03.040 | - |
| Language | en | - |
| Extent | 5 pages | en |
| Title | Catalytic and electrocatalytic behavior of Ni-based cermet anodes under internal dry reforming of CH4 + CO2 mixtures in SOFCs | en |
| Creator | Gentekakis Ioannis | en |
| Creator | Γεντεκακης Ιωαννης | el |
| Creator | Nalbandian L. | en |
| Creator | Kiousis V. | en |
| Creator | Goula G. | en |
| Publisher | Elsevier | en |
| Content Summary | A high temperature (700–900 °C) SOFC with yttria stabilized zirconia (YSZ) solid electrolyte was constructed and tested on direct feed of simulated biogas (CH4 + CO2) mixtures. Both catalytic, i.e. open-circuit, and electrocatalytic, i.e. closed-circuit, measurements were carried out. Open-circuit kinetic data showed that the rate of the catalytic reaction of the dry(CO2)-reforming of methane is maximized at about equimolar CO2/CH4 feed ratio for all temperatures studied. Closed-circuit data showed that cell output characteristics (i.e. current and power densities) are also maximized for equimolar CO2/CH4 biogas composition. Power densities up to 51.6 mW/cm2 (at V = 453 mV, i = 114 mA/cm2, T = 875 °C) have been obtained. Long-term operation experiments demonstrated that the constructed biogas fuel cell has very stable behavior for all three different simulated biogas compositions fed, including poor, equimolar and rich methane constitutions. | en |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-11-16 | - |
| Date of Publication | 2006 | - |
| Subject | YSZ–SOFC | en |
| Subject | Biogas | en |
| Subject | Methane internal dry reforming | en |
| Subject | Ni cermet | en |
| Subject | Perovskite | en |
| Bibliographic Citation | G. Goula, V. Kiousis, L. Nalbandian and I. V. Yentekakis, "Catalytic and electrocatalytic behavior of Ni-based cermet anodes under internal dry reforming of CH4 + CO2 mixtures in SOFCs", Solid State Ion., vol. 177, no. 19-25, pp. 2119-2123, Oct. 2006. doi:10.1016/j.ssi.2006.03.040 | en |
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