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Effects of heating rate and water leaching of perennial energy crops on pyrolysis characteristics and kinetics

Vamvouka Despoina, Sfakiotakis Stylianos

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URIhttp://purl.tuc.gr/dl/dias/E58CE5DD-6E62-4A78-99EE-464617BAD5E8-
Identifierhttps://doi.org/10.1016/j.renene.2011.02.013-
Identifierhttp://www.sciencedirect.com/science/article/pii/S0960148111000899-
Languageen-
Extent7 pagesen
TitleEffects of heating rate and water leaching of perennial energy crops on pyrolysis characteristics and kineticsen
CreatorVamvouka Despoinaen
CreatorΒαμβουκα Δεσποιναel
CreatorSfakiotakis Stylianosen
CreatorΣφακιωτακης Στυλιανοςel
PublisherElsevieren
Content SummaryAiming to investigate the suitability of perennial crops for heat and power applications, three energy crops produced under the Greek climatic conditions were pyrolyzed by non-isothermal thermog-ravimetry over the temperature range of 25e850 C. The effects of heating rate and water washing of the fuels on thermal decomposition characteristics, reactivity and kinetics were examined. The thermochemical reactivity of the biomass materials was determined by their volatile and ash contents, as well as the distribution of organic and inorganic constituents among plant parts. Switchgrass leaves exhibited the highest pyrolysis rate, while cardoon leaves the lowest. An increase of the heating rate delayed thermal decomposition processes and increased degradation rates. Raw fuel washing enhanced reaction rates of switchgrass and giant reed, whereas it influenced the sensitivity of cardoon in nitrogen, by shifting the peak temperature to higher values. A first-order parallel reactions model fitted the experimental results accurately. A higher heating rate, or a lower content of K, P, S and Cl in ashes increased the kinetic parameters corresponding to hemicellulose and cellulose decomposition.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-11-17-
Date of Publication2011-
SubjectAlternate energy sourcesen
SubjectAlternative energy sourcesen
SubjectEnergy sources, Renewableen
SubjectRenewable energy resourcesen
SubjectSustainable energy sourcesen
Subjectrenewable energy sourcesen
Subjectalternate energy sourcesen
Subjectalternative energy sourcesen
Subjectenergy sources renewableen
Subjectrenewable energy resourcesen
Subjectsustainable energy sourcesen
Bibliographic CitationD. Vamvouka and S.I. Sfakiotakis, "Effects of heating rate and water leaching of perennial energy crops on pyrolysis characteristics and kinetics", Renewable Energy, vol. 36, no. 9, Sep. 2011. doi: 10.1016/j.renene.2011.02.013en

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