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Sequential application of chelating agents and innovative surfactants for the enhanced electroremediation of real sediments from toxic metals and PAHs

Gidarakos Evaggelos, Sbonias Andreas, Lekkas Nikolaos, Chachladakis Ioannis

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URIhttp://purl.tuc.gr/dl/dias/412BFD43-CDF7-473C-8184-1A37DE225BBA-
Identifierhttp://www.sciencedirect.com/science/article/pii/S0045653513016123-
Identifierhttps://doi.org/10.1016/j.chemosphere.2013.11.022-
Languageen-
Extent9 pagesel
TitleSequential application of chelating agents and innovative surfactants for the enhanced electroremediation of real sediments from toxic metals and PAHsen
CreatorGidarakos Evaggelosen
CreatorΓιδαρακος Ευαγγελοςel
CreatorSbonias Andreasen
CreatorΣμπονιας Ανδρεαςel
CreatorLekkas Nikolaosen
CreatorΛεκκας Νικολαοςel
CreatorChachladakis Ioannisen
CreatorΧαχλαδακης Ιωαννηςel
PublisherElsevieren
Content SummaryThis study focused on the sequential application of a chelating agent (citric acid) followed by a surfactant in the simultaneous electroremediation of real contaminated sediments from toxic metals and Polycyclic Aromatic Hydrocarbons (PAHs). Furthermore, the efficiency evaluation of two innovative non-ionic surfactants, commercially known as Poloxamer 407 and Nonidet P40, was investigated. The results indicated a removal efficacy of approximately 43% and 48% for the summation of PAHs (SUM PAHs), respectively for the aforementioned surfactants, much better than the one obtained by the use of Tween 80 (nearly 21%). Individual PAHs (e.g. fluorene) were removed in percentages that reached almost 84% and 92% in the respective electrokinetic experiments when these new surfactants were introduced. In addition, the combined-enhanced sequential electrokinetic treatment with citric acid improved dramatically the removal of Zn and As, compared to the unenhanced run, but did not favor the other toxic metals examined. Since no improvement in metal removal percentages occurred when Tween 80 was used, significant contribution to this matter should also be attributed to the solubilization capacity of these innovative, in electrokinetic remediation, non-ionic surfactants.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-11-17-
Date of Publication2014-
SubjectElectrokinetic remediationen
SubjectSedimentsen
SubjectPAHsen
SubjectToxic metalsen
SubjectSurfactantsen
Bibliographic CitationJ. N. Hahladakis, N. Lekkas, A. Smponias and E. Gidarakos, "Sequential application of chelating agents and innovative surfactants for the enhanced electroremediation of real sediments from toxic metals and PAHs", Chemosph., vol. 105, pp. 44-52, Jun. 2014. doi:10.1016/j.chemosphere.2013.11.022en

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