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Ca doped YBCO on the Ba site

Liarokapis, E, Perdikatsis Vasilis, M. Calamiotou, G. A. Soifer, Th. Leventouri

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URIhttp://purl.tuc.gr/dl/dias/2CF90862-E6E5-461E-8FF8-F2F4CF861D07-
Identifierhttp://link.springer.com/article/10.1007/BF00727448-
Identifierhttps://doi.org/10.1007/BF00727448-
Languageen-
Extent2 pagesen
TitleCa doped YBCO on the Ba siteen
CreatorLiarokapis, Een
CreatorPerdikatsis Vasilisen
CreatorΠερδικατσης Βασιληςel
CreatorM. Calamiotouen
Creator G. A. Soiferen
CreatorTh. Leventourien
PublisherKluweren
Content SummaryThe effect of partial, nominal replacement of Ba with Ca on the properties of the YBa2Cu3O6+gd superconductor varies with the concentration of Ca. For nominal concentrations in Ca up to 50% a two phase system is formed: the known superconducting phase Y1−yCayBa2Cu3O6+δ and a new, non superconducting phase of composition Y1.14Ca1.58Cu3.27O6.45. The x-ray diffraction pattern of this new phase matches the Bragg peaks, as well as the commensurate and incommensurate peaks of a partially indexed pattern of the phase Y2−xCa2+xCu5O10. For nominal Ca concentrations 40 and 50%, microprobe analysis shows that the superconducting phase becomes a mixture of Y1−yCayBa2Cu3O6+° and YBa1.8Ca0.2Cu3O6.5, where Ca enters the structure in the Ba site. The microraman spectra indicate a small substitution of Ba by Ca, while the new phase shows novel characteristics.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-12-03-
Date of Publication1995-
SubjectCa substitutions en
Subjectsuperconductorsen
Subject new phaseen
Bibliographic CitationT. Leventouri, G. A. Soifer, M. Calamiotou, V. Perdikatsis, and E. Liarokapis, "Ca doped YBCO on the Ba site", J. Superconduct., vol. 8, no. 5, pp. 625-626, Oct. 1995. doi:10.1007/BF00727448en

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