Institutional Repository
Technical University of Crete
Technical University of Crete
EN
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| URI: | http://purl.tuc.gr/dl/dias/BEA2BE96-D77D-4920-A862-6128B13A5D56 | ||
| Year | 2013 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | V. N. Dokorou, A. K. Powell, and G. E. Kostakis, "Two pseudopolymorphs derived from alkaline earth metals and the pseudopeptidic ligand trimesoyl-tris-glycine", Polyhedron, vol. 52, pp. 528-544, Mar. 2013. doi:10.1016/j.poly.2012.08.032 https://doi.org/10.1016/j.poly.2012.08.032 | ||
| Appears in Collections |
The reaction of Ca(NO3)2·3H2O and Sr(NO3)2 with trimesoyl-tris-glycine (H3L) leads to a two dimensional (2D) [Ca2(HL)2(μ-H2O)(H2O)5]·3H2O (1) and a three dimensional (3D) [Sr2(HL)2(H2O)7]·H2O (2) coordination polymer, respectively, illustrating the substantial influence of the ionic radii of the alkaline earth metals in determining the motif of the final product.
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