The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole]
Kostakis Georgios, Pantelis Xydias, Ebbe Nordlander, Plakatouras, John C
Το work with title The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] by Kostakis Georgios, Pantelis Xydias, Ebbe Nordlander, Plakatouras, John C is licensed under Creative Commons Attribution 4.0 International
Bibliographic Citation
G. E. Kostakis, P. Xydias, E. Nordlander, and J. C. Plakatouras, "The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole]", Inorganica Chim. Acta, vol. 383, pp. 327-331, Mar. 2012. doi:10.1016/j.ica.2011.10.063
https://doi.org/10.1016/j.ica.2011.10.063
The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1,2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]·2CH3CN (1·2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV–Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar.