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A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates

David Specklin, Samir Mameri, Edward Loukopoulos, Kostakis Georgios, Richard Welter

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URI: http://purl.tuc.gr/dl/dias/0A30B500-ACD5-41FF-90D5-FB28AF3C9905
Year 2015
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation D. Specklin, S. Mameri, E. Loukopoulos, G. E. Kostakis, and R. Welter, "A synthetic and crystal structure study of a collection of coordination polymers based on alkaline aroylhydrazonates", Polyhedron, vol. 100, pp. 359-372, Nov. 2015. doi:10.1016/j.poly.2015.08.013 https://doi.org/10.1016/j.poly.2015.08.013
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Summary

The reactions of two aroylhydrazone ligands H2LS and H2LAc with alkaline Li(I), Na(I), K(I) and Ba(II) metal ions afforded nine new coordination polymers with different dimensionalities. These illustrate the ionic radii, the ligand substitution and the solvent influence on the formation of the final product. Interestingly, one of them shows porous structure with a 40% unoccupied volume.

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