Institutional Repository
Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/B30DDA7F-7520-4BAA-B639-5E6841E6AA76 | ||
| Year | 2011 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | G. E. Kostakis, E. Nordlander, A. C. Tsipis, M. Haukka, and J. C. Plakatouras, "Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]∙3(H2O)}2 (H3L = trans-aconitic acid)", Inorganic Chem. Communicat., vol. 14, no. 1, pp. 87-91, Jan. 2011. doi:10.1016/j.inoche.2010.09.038 https://doi.org/10.1016/j.inoche.2010.09.038 | ||
| Appears in Collections |
The reaction of Zn(NO3)2∙3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]∙3(H2O)}2. The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented.
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