Institutional Repository
Technical University of Crete
Technical University of Crete
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| URI | http://purl.tuc.gr/dl/dias/B30DDA7F-7520-4BAA-B639-5E6841E6AA76 | - |
| Identifier | http://www.sciencedirect.com/science/article/pii/S1387700310004429 | - |
| Identifier | https://doi.org/10.1016/j.inoche.2010.09.038 | - |
| Language | en | - |
| Extent | 5 pages | en |
| Title | Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]∙3(H2O)}2 (H3L = trans-aconitic acid) | en |
| Creator | Kostakis Georgios | en |
| Creator | Κωστακης Γεωργιος | el |
| Creator | Ebbe Nordlander | en |
| Creator | Athanassios C. Tsipis | en |
| Creator | Matti Haukka | en |
| Creator | Plakatouras, John C | en |
| Publisher | Elsevier | en |
| Content Summary | The reaction of Zn(NO3)2∙3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]∙3(H2O)}2. The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. | en |
| Type of Item | Peer-Reviewed Journal Publication | en |
| Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
| License | http://creativecommons.org/licenses/by/4.0/ | en |
| Date of Item | 2015-12-03 | - |
| Date of Publication | 2011 | - |
| Subject | Hexameric water cluster | en |
| Subject | Zinc(II) | en |
| Subject | 3D metal-supramolecular architecture | en |
| Subject | H-bond | en |
| Subject | Crystal structure | en |
| Bibliographic Citation | G. E. Kostakis, E. Nordlander, A. C. Tsipis, M. Haukka, and J. C. Plakatouras, "Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]∙3(H2O)}2 (H3L = trans-aconitic acid)", Inorganic Chem. Communicat., vol. 14, no. 1, pp. 87-91, Jan. 2011. doi:10.1016/j.inoche.2010.09.038 | en |
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