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Synthesis and characterization of isostructural tetranuclear lanthanide complexes [Ln4(μ3-OH)2(ampdH4)2(piv)10]·4CH3CN (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er)

Annie K. Powell, Yanhua Lan, Ghulam Abbas, Kostakis Georgios

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URIhttp://purl.tuc.gr/dl/dias/70C5431B-1F1E-4849-9B15-FB8155DF0ED6-
Identifierhttp://www.sciencedirect.com/science/article/pii/S027753871200160X-
Identifierhttps://doi.org/10.1016/j.poly.2012.03.022-
Languageen-
Extent6 pagesen
TitleSynthesis and characterization of isostructural tetranuclear lanthanide complexes [Ln4(μ3-OH)2(ampdH4)2(piv)10]·4CH3CN (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er)en
CreatorAnnie K. Powellen
CreatorYanhua Lanen
CreatorGhulam Abbasen
CreatorKostakis Georgiosen
CreatorΚωστακης Γεωργιοςel
PublisherElsevieren
Content SummaryA series of seven isostructural lanthanide tetramers of general formula [Ln4(μ3-OH)2(ampdH4)2(piv)10] 4CH3CN, where ampdH4 is 3-amino-3-methylpentane-1,5-diol, piv is pivalate, and Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6) and Er (7) have been successfully synthesized and characterized. Magnetic studies on the DyIII analogue show weak intramolecular coupling within the four DyIII ions and Single Molecule Magnet (SMM) behaviour.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-12-04-
Date of Publication2012-
SubjectLanthanidesen
SubjectMagnetismen
SubjectCrystal structureen
Subject3-Amino-3-methylpentane-1,5-diolen
Bibliographic CitationG. Abbas, G. E. Kostakis, Y. Lan, and A. K. Powell, "Synthesis and characterization of isostructural tetranuclear lanthanide complexes [Ln4(μ3-OH)2(ampdH4)2(piv)10]·4CH3CN (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er)", Polyhedron, vol. 41, no. 1, pp. 1-6, Jun. 2012. doi:10.1016/j.poly.2012.03.022en

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