URI | http://purl.tuc.gr/dl/dias/70C5431B-1F1E-4849-9B15-FB8155DF0ED6 | - |
Identifier | http://www.sciencedirect.com/science/article/pii/S027753871200160X | - |
Identifier | https://doi.org/10.1016/j.poly.2012.03.022 | - |
Language | en | - |
Extent | 6 pages | en |
Title | Synthesis and characterization of isostructural tetranuclear lanthanide complexes [Ln4(μ3-OH)2(ampdH4)2(piv)10]·4CH3CN (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er) | en |
Creator | Annie K. Powell | en |
Creator | Yanhua Lan | en |
Creator | Ghulam Abbas | en |
Creator | Kostakis Georgios | en |
Creator | Κωστακης Γεωργιος | el |
Publisher | Elsevier | en |
Content Summary | A series of seven isostructural lanthanide tetramers of general formula [Ln4(μ3-OH)2(ampdH4)2(piv)10] 4CH3CN, where ampdH4 is 3-amino-3-methylpentane-1,5-diol, piv is pivalate, and Ln = Sm (1), Eu (2), Gd (3), Tb (4), Dy (5), Ho (6) and Er (7) have been successfully synthesized and characterized. Magnetic studies on the DyIII analogue show weak intramolecular coupling within the four DyIII ions and Single Molecule Magnet (SMM) behaviour. | en |
Type of Item | Peer-Reviewed Journal Publication | en |
Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
License | http://creativecommons.org/licenses/by/4.0/ | en |
Date of Item | 2015-12-04 | - |
Date of Publication | 2012 | - |
Subject | Lanthanides | en |
Subject | Magnetism | en |
Subject | Crystal structure | en |
Subject | 3-Amino-3-methylpentane-1,5-diol | en |
Bibliographic Citation | G. Abbas, G. E. Kostakis, Y. Lan, and A. K. Powell, "Synthesis and characterization of isostructural tetranuclear lanthanide complexes [Ln4(μ3-OH)2(ampdH4)2(piv)10]·4CH3CN (Ln = Sm, Eu, Gd, Tb, Dy, Ho, Er)", Polyhedron, vol. 41, no. 1, pp. 1-6, Jun. 2012. doi:10.1016/j.poly.2012.03.022 | en |