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Technical University of Crete
Technical University of Crete
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| URI: | http://purl.tuc.gr/dl/dias/A96E6F54-0948-4F0E-B302-47DBAEF14667 | ||
| Year | 2010 | ||
| Type of Item | Peer-Reviewed Journal Publication | ||
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| Bibliographic Citation | G. E. Kostakis, K. C. Mondal, C. E. Anson, and A. K. Powell, "Influence of the metal radius on the dimensionality of hydrogen-bonded metal supramolecular frameworks in the metal/p-BDTH2 (1,4-benzeneditetrazol-5-yl) reaction system", Polyhedron, vol. 29, no. 1, pp. 24-29, Jan. 2010. doi:10.1016/j.poly.2009.05.057 https://doi.org/10.1016/j.poly.2009.05.057 | ||
| Appears in Collections |
The reaction of Mn(NO3)2·6H2O and Ce(NO3)3·6(H2O) with p-BDTH2 (1,4-benzeneditetrazol-5-yl) leads to a two dimensional (2D) [Mn(H2O)6](p-BDTH)2·2H2O (1) and a three dimensional (3D) [Ce(H2O)8.64](p-BDT)(p-BDTH)·6H2O (2) hydrogen-bonded frameworks, respectively. The topological description of the metal supramolecular architectures reveals a binodal (3,6) net with topological type kgd for 1 and a rare binodal (4,8) net with topological type scu for 2.
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