URI | http://purl.tuc.gr/dl/dias/1A811727-3D99-4991-AF69-9FC9ED098B51 | - |
Identifier | http://www.sciencedirect.com/science/article/pii/S0040403914013823 | - |
Identifier | https://doi.org/10.1016/j.tetlet.2014.08.048 | - |
Language | en | - |
Extent | 4 pages | en |
Title | Chromeno[2,3-c]pyrroles by one-pot multicomponent domino addition–amination reaction | en |
Creator | Michael A. Terzidis | en |
Creator | Vassilios G. Tsiaras | en |
Creator | Nicolaos M. Drosos | en |
Creator | Paraskevi M. Kasapidou | en |
Creator | Julia Stephanidou-Stephanatou | en |
Creator | Constantinos A. Tsoleridis | en |
Creator | Gernot Buth | en |
Creator | Kostakis Georgios | en |
Creator | Κωστακης Γεωργιος | el |
Publisher | Elsevier | en |
Content Summary | A new aspect concerning chromone chemistry leading to the one-pot synthesis of chromeno[2,3-c]pyrroles is described. The synthesis involves a multicomponent reaction of 3-formylchromones with isocyanides and azodicarboxylates, whereupon novel chromeno[2,3-c]pyrrole derivatives were formed in good yields. The structures of the products were elucidated by 1D and 2D NMR experiments and were unambiguously confirmed by the use of crystal X-ray diffraction analysis. Full assignment of all 1H and 13C NMR chemical shifts has been achieved. A plausible mechanistic scheme is proposed. | en |
Type of Item | Peer-Reviewed Journal Publication | en |
Type of Item | Δημοσίευση σε Περιοδικό με Κριτές | el |
License | http://creativecommons.org/licenses/by/4.0/ | en |
Date of Item | 2015-12-04 | - |
Date of Publication | 2014 | - |
Subject | Azodicarboxylates | en |
Subject | Chromeno[2,3-c]pyrroles | en |
Subject | Formylchromones | en |
Subject | Isocyanides | en |
Subject | Multicomponent reactions | en |
Bibliographic Citation | M. A. Terzidis, V. G. Tsiaras, N. M. Drosos, P. M. Kasapidou, J. Stephanidou-Stephanatou, C. A. Tsoleridis, G. Buth, and G. E. Kostakis, "Chromeno[2,3-c]pyrroles by one-pot multicomponent domino addition–amination reaction", Tetrahedron Lett., vol. 55, no. 41, pp. 5601-5604, Oct. 2014. doi:10.1016/j.tetlet.2014.08.048 | en |