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Chromeno[2,3-c]pyrroles by one-pot multicomponent domino addition–amination reaction

Michael A. Terzidis, Vassilios G. Tsiaras, Nicolaos M. Drosos, Paraskevi M. Kasapidou, Julia Stephanidou-Stephanatou, Constantinos A. Tsoleridis, Gernot Buth, Kostakis Georgios

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URIhttp://purl.tuc.gr/dl/dias/1A811727-3D99-4991-AF69-9FC9ED098B51-
Identifierhttp://www.sciencedirect.com/science/article/pii/S0040403914013823-
Identifierhttps://doi.org/10.1016/j.tetlet.2014.08.048-
Languageen-
Extent4 pagesen
TitleChromeno[2,3-c]pyrroles by one-pot multicomponent domino addition–amination reactionen
CreatorMichael A. Terzidisen
CreatorVassilios G. Tsiarasen
CreatorNicolaos M. Drososen
CreatorParaskevi M. Kasapidouen
Creator Julia Stephanidou-Stephanatouen
CreatorConstantinos A. Tsoleridisen
CreatorGernot Buthen
CreatorKostakis Georgiosen
CreatorΚωστακης Γεωργιοςel
PublisherElsevieren
Content SummaryA new aspect concerning chromone chemistry leading to the one-pot synthesis of chromeno[2,3-c]pyrroles is described. The synthesis involves a multicomponent reaction of 3-formylchromones with isocyanides and azodicarboxylates, whereupon novel chromeno[2,3-c]pyrrole derivatives were formed in good yields. The structures of the products were elucidated by 1D and 2D NMR experiments and were unambiguously confirmed by the use of crystal X-ray diffraction analysis. Full assignment of all 1H and 13C NMR chemical shifts has been achieved. A plausible mechanistic scheme is proposed.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-12-04-
Date of Publication2014-
SubjectAzodicarboxylatesen
SubjectChromeno[2,3-c]pyrrolesen
SubjectFormylchromonesen
SubjectIsocyanidesen
SubjectMulticomponent reactionsen
Bibliographic CitationM. A. Terzidis, V. G. Tsiaras, N. M. Drosos, P. M. Kasapidou, J. Stephanidou-Stephanatou, C. A. Tsoleridis, G. Buth, and G. E. Kostakis, "Chromeno[2,3-c]pyrroles by one-pot multicomponent domino addition–amination reaction", Tetrahedron Lett., vol. 55, no. 41, pp. 5601-5604, Oct. 2014. doi:10.1016/j.tetlet.2014.08.048en

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