Ιδρυματικό Αποθετήριο
Πολυτεχνείο Κρήτης
Πολυτεχνείο Κρήτης
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| URI | http://purl.tuc.gr/dl/dias/2700E6D8-A447-4C6C-BA09-43D0090F7397 | - |
| Αναγνωριστικό | https://www.sciencedirect.com/science/article/pii/S2212982017303074?via%3Dihub | - |
| Αναγνωριστικό | https://doi.org/10.1016/j.jcou.2017.08.019 | - |
| Γλώσσα | en | - |
| Μέγεθος | 10 pages | en |
| Τίτλος | Effect of support nature on the cobalt-catalyzed CO2 hydrogenation | en |
| Δημιουργός | Díez-Ramírez J. | en |
| Δημιουργός | Sánchez, Paula | en |
| Δημιουργός | Kyriakou Vasileios | en |
| Δημιουργός | Zafeiratos, Spyridon, 19..- | en |
| Δημιουργός | Marnellos, Georges E | en |
| Δημιουργός | Konsolakis Michail | en |
| Δημιουργός | Κονσολακης Μιχαηλ | el |
| Δημιουργός | Dorado Fernando | en |
| Εκδότης | Elsevier | en |
| Περίληψη | CO2 hydrogenation to value added chemicals/fuels has gained considerable interest, in terms of sustainable energy and environmental mitigation. In this regard, the present work aims to investigate the CO2 methanation performance of cobalt-based catalysts supported on different metal oxides (MxOy: CeO2, ZrO2, Gd2O3, ZnO) at low temperatures (200-300 °C) and under atmospheric pressure. Various characterization methods, such as N2 adsorption-desorption at -196 °C, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and temperature-programmed reduction (TPR), were employed to correlate the structural and surface properties of the materials with their catalytic activity. The results revealed a significant impact of support nature on the CO2 hydrogenation performance. The following order, in terms of CH4 yield (YCH4), was recorded at 300 °C: Co/CeO2 (∼96%) > Co/ZnO (∼54%) > Co/G2O3 (∼53%) ∼ Co/ZrO2 (∼53%). On the basis of the characterization results, the superiority of Co/CeO2 catalyst can be mainly ascribed to its enhanced reducibility linked to Co-Ceria interactions. Moreover, Co/CeO2 demonstrated a stable conversion/selectivity performance under subsequent reaction cycles, in contrast to Co/ZnO, which progressively activated under reaction conditions. The latter is related with the modifications induced in elemental chemical states and surface composition of Co/ZnO upon pretreatment in reaction conditions, in contrast to Co/CeO2 sample where a stable surface performance was observed. | en |
| Τύπος | Peer-Reviewed Journal Publication | en |
| Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | el |
| Άδεια Χρήσης | http://creativecommons.org/licenses/by/4.0/ | en |
| Ημερομηνία | 2018-03-28 | - |
| Ημερομηνία Δημοσίευσης | 2017 | - |
| Θεματική Κατηγορία | Co-based catalysts | en |
| Θεματική Κατηγορία | CO2 hydrogenation | en |
| Θεματική Κατηγορία | Methanation | en |
| Βιβλιογραφική Αναφορά | J. Díez-Ramírez, P. Sánchez, V. Kyriakou, S. Zafeiratos, G. E. Marnellos, M. Konsolakis and F. Dorado, "Effect of support nature on the cobalt-catalyzed CO2 hydrogenation," J. CO2 Util., vol. 21, pp. 562-571, Oct. 2017. doi: 10.1016/j.jcou.2017.08.019 | en |
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