Ιδρυματικό Αποθετήριο
Πολυτεχνείο Κρήτης
Πολυτεχνείο Κρήτης
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| URI: | http://purl.tuc.gr/dl/dias/1701BDDF-0BC0-4F92-8C11-2C5D4D39001C | ||
| Έτος | 2018 | ||
| Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | ||
| Άδεια Χρήσης |
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| Βιβλιογραφική Αναφορά | T. Makropoulou, P. Panagiotopoulou and D. Venieri, "N-doped TiO2 photocatalysts for bacterial inactivation in water", J. Chem. Technol. Biotechnol., vol. 93, no. 9, pp. 2518-2526, Sept. 2018. doi: 10.1002/jctb.5639 https://doi.org/10.1002/jctb.5639 | ||
| Εμφανίζεται στις Συλλογές |
The elimination of diverse and pathogenic microbial loads in water imposes the exploration of effective disinfection techniques. The current study focused on the synthesis of N-TiO2 photocatalysts and the investigation of their disinfection potential, in terms of Escherichia coli, Pseudomonas aeruginosa and Bacillus cereus inactivation in aqueous samples under artificial sunlight. N-TiO2 photocatalysts were synthesized using various nitrogen precursors [urea, triethylamine-(TEA) and NH3], exhibiting narrow band gaps and improved visible light response. The relative bactericidal activity of the catalysts followed the order N-TiO2 (UREA) > N-TiO2 (NH3)∼N-TiO2 (TEA) > synthesized TiO2 > TiO2-P25. The Gram-negative indicators E. coli and P. aeruginosa, were readily inactivated, reaching reduction rates up to 6 log10 within 60 min of treatment at an initial bacterial concentration of 106 CFU mL−1 and a catalyst concentration of 50 mg L−1. The activity discrepancies among the catalysts were more pronounced in the case of B. cereus, which showed higher resistance, thus exhibiting slower inactivation rates. Complete elimination was achieved only with N-TiO2 (TEA) within 60 min of irradiation at a loading of 100 mg L−1. Increasing the TEA concentration for the preparation of this catalyst from 25 to 89 v/v% did not enhance significantly the process. Operating conditions, including catalyst concentration, nitrogen precursor and, especially, bacterial species defined the disinfection efficiency up to a certain extent. Solar photocatalysis with N-TiO2 catalysts may be an effective disinfection technology if the operational conditions are established in relation to the microbial content in water, which includes opportunistic pathogens such as P. aeruginosa and B. cereus.
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