Ιδρυματικό Αποθετήριο
Πολυτεχνείο Κρήτης
Πολυτεχνείο Κρήτης
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| URI | http://purl.tuc.gr/dl/dias/1C605598-5D5A-4E2B-895B-B0298A3FDB30 | - |
| Αναγνωριστικό | https://doi.org/10.1016/j.ssi.2018.01.026 | - |
| Αναγνωριστικό | https://www.sciencedirect.com/science/article/pii/S0167273817307683 | - |
| Γλώσσα | en | - |
| Μέγεθος | 8 pages | en |
| Τίτλος | The combined impact of carbon type and catalyst-aided gasification process on the performance of a Direct Carbon Solid Oxide Fuel Cell | en |
| Δημιουργός | Konsolakis Michail | en |
| Δημιουργός | Κονσολακης Μιχαηλ | el |
| Δημιουργός | Kaklidis Nikolaos | en |
| Δημιουργός | Kyriakou Vasileios | en |
| Δημιουργός | Garagounis Ioannis | en |
| Δημιουργός | Kraia Tzouliana | en |
| Δημιουργός | Arenillas Ana | en |
| Δημιουργός | Menéndez José Ángel | en |
| Δημιουργός | Strandbakke Ragnar | en |
| Δημιουργός | Marnellos, Georges E | en |
| Εκδότης | Elsevier | en |
| Περίληψη | The combined impact of carbon type (anthracite coal, bituminous coal and pine charcoal) and in situ, catalyst-aided, carbon gasification process on the electrochemical performance of a Direct Carbon Fuel Cell (DCFC) is explored. The effect of operation temperature (700–800 °C) and catalyst (Co/CeO2) infusion to carbon feedstock under CO2 atmosphere at the anode chamber is systematically investigated in a cell of the type: Carbon + CO2|Cu-CeO2/YSZ/Ag|Air. All fuel samples were characterized, in terms of chemical composition, crystallite structure (XRD), pore structure (BET), surface morphology (SEM), particle size distribution (PSD) and thermogravimetric analysis (TGA), in order to obtain a close relationship between the carbon characteristics and the DCFC performance. The results reveal that in the absence of catalyst, the optimum performance is obtained for the charcoal sample (Pmax ~ 12 mW/cm2), due to its high volatile matter, oxygen content, porosity and carbon disorder as well as its low amount of impurities. Catalyst infusion to carbon feedstock results in a considerable increase in the achieved cell power density up to 225%, which is more pronounced for the less reactive coals and low temperatures. The enhanced performance obtained by infusing Co/CeO2 catalyst into carbon is ascribed to the positive effect of catalyst on the in situ carbon gasification, through the reverse Boudouard reaction (C + CO2 → 2CO), and the subsequent faster diffusion and electro-oxidation of formed CO at the anodic three-phase boundary. | en |
| Τύπος | Peer-Reviewed Journal Publication | en |
| Τύπος | Δημοσίευση σε Περιοδικό με Κριτές | el |
| Άδεια Χρήσης | http://creativecommons.org/licenses/by/4.0/ | en |
| Ημερομηνία | 2019-09-20 | - |
| Ημερομηνία Δημοσίευσης | 2018 | - |
| Θεματική Κατηγορία | Anthracite coal | en |
| Θεματική Κατηγορία | Bituminous coal | en |
| Θεματική Κατηγορία | Co/CeO2 catalyst | en |
| Θεματική Κατηγορία | Direct Carbon Fuel Cell | en |
| Θεματική Κατηγορία | Internal catalytic gasification | en |
| Θεματική Κατηγορία | Pine charcoal | en |
| Βιβλιογραφική Αναφορά | M. Konsolakis, N. Kaklidis, V. Kyriakou, I. Garagounis, T. Kraia, A. Arenillas, J.A. Menéndez, R. Strandbakke and G.E. Marnellos, "The combined impact of carbon type and catalyst-aided gasification process on the performance of a Direct Carbon Solid Oxide Fuel Cell," Solid State Ion., vol. 317, pp. 268-275, Apr. 2018. doi: 10.1016/j.ssi.2018.01.026 | en |
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