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Surface plasmon resonance study of adhesion kinetics of smectites on the Au/water interface: clay and organo-clay film formation

Κουτσοπούλου Ελένη, Papagiannopoulos Aristeidis, Christidis Georgios, Tassis George, Spiliopoulos Nikolaos

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/D1565092-149A-4C72-BD83-59FDBB800E12-
Αναγνωριστικόhttps://doi.org/10.1016/j.clay.2019.03.012-
Αναγνωριστικόhttps://www.sciencedirect.com/science/article/pii/S0169131719300821?via%3Dihub-
Γλώσσαen-
Μέγεθος9 pagesen
ΤίτλοςSurface plasmon resonance study of adhesion kinetics of smectites on the Au/water interface: clay and organo-clay film formationen
ΔημιουργόςΚουτσοπούλου Ελένηel
ΔημιουργόςKoutsopoulou Elenien
ΔημιουργόςPapagiannopoulos Aristeidisen
ΔημιουργόςChristidis Georgiosen
ΔημιουργόςΧρηστιδης Γεωργιοςel
ΔημιουργόςTassis Georgeen
ΔημιουργόςSpiliopoulos Nikolaosen
ΕκδότηςElsevieren
ΠερίληψηSurface plasmon resonance was employed for the in-situ investigation of film formation from aqueous dispersions of clay minerals on gold/water interface. High charge (SAz-1) and intermediate charge smectite (STx-1b) were studied for their ability to form stable clay films on gold surfaces and their adhesion kinetics at different concentrations was investigated. Layer charge and charge distribution seems to affect not only the kinetics of film formation but also the overall amount of clay mineral on the gold substrate. Subsequently to stable clay mineral film formation, the in-situ preparation of hybrid organo-clay films with the introduction of alkylammonium chains and their adsorption kinetics was examined. Alkylammonium adsorption via ion exchange in the interlayer of the clay minerals is controlled by the density of the clay mineral film in full accordance with layer charge and charge localization. Hence, a simple self-assembly procedure for the in-situ preparation of hybrid organo-clay films for novel applications is proposed.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2020-05-28-
Ημερομηνία Δημοσίευσης2019-
Θεματική ΚατηγορίαClay filmen
Θεματική ΚατηγορίαLayer chargeen
Θεματική ΚατηγορίαOrgano-clay film formationen
Θεματική ΚατηγορίαSelf-assemblyen
Θεματική ΚατηγορίαSmectiteen
Θεματική ΚατηγορίαSurface plasmon resonanceen
Βιβλιογραφική ΑναφοράΕ. Koutsopoulou, A. Papagiannopoulos, G.E. Christidis, G. Tassis and N. Spiliopoulos, "Surface plasmon resonance study of adhesion kinetics of smectites on the Au/water interface: clay and organo-clay film formation," Appl. Clay Sci., vol. 175, pp. 1-9, Jul. 2019. doi: 10.1016/j.clay.2019.03.012el

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