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Effect of clay colloid particles on formaldehyde transport in unsaturated porous media

Fountouli Theodosia, Chrysikopoulos Constantinos

Απλή Εγγραφή


URIhttp://purl.tuc.gr/dl/dias/96BC9DBD-16AC-40BF-9EC2-1AD4F68D64E3-
Αναγνωριστικόhttps://doi.org/10.3390/w12123541-
Αναγνωριστικόhttps://www.mdpi.com/2073-4441/12/12/3541-
Γλώσσαen-
Μέγεθος16 pagesen
Μέγεθος2,57 Megabytesen
ΤίτλοςEffect of clay colloid particles on formaldehyde transport in unsaturated porous mediaen
ΔημιουργόςFountouli Theodosiaen
ΔημιουργόςΦουντουλη Θεοδοσιαel
ΔημιουργόςChrysikopoulos Constantinosen
ΔημιουργόςΧρυσικοπουλος Κωνσταντινοςel
ΕκδότηςMDPIen
ΠερίληψηThis study examines the effects of two representative colloid-sized clay particles (kaolinite, KGa-1b and montmorillonite, STx-1b) on the transport of formaldehyde (FA) in unsaturated porous media. The transport of FA was examined with and without the presence of clay particles under various flow rates and various levels of saturation in columns packed with quartz sand, under unsaturated conditions. The experimental results clearly suggested that the presence of clay particles retarded by up to ~23% the transport of FA in unsaturated packed columns. Derjaguin–Landau–Verwey–Overbeek (DLVO) interaction energy calculations demonstrated that permanent retention of clay colloids at air-water interfaces (AWI) and solid-water interfaces (SWI) was negligible, except for the pair (STx-1b)–SWI. The experimental results of this study showed that significant clay colloid retention occurred in the unsaturated column, especially at low flow rates. This deviation from DLVO predictions may be explained by the existence of additional non-DLVO forces (hydrophobic and capillary forces) that could be much stronger than van der Waals and double layer forces. The present study shows the important role of colloids, which may act as carriers of contaminants.en
ΤύποςPeer-Reviewed Journal Publicationen
ΤύποςΔημοσίευση σε Περιοδικό με Κριτέςel
Άδεια Χρήσηςhttp://creativecommons.org/licenses/by/4.0/en
Ημερομηνία2021-03-29-
Ημερομηνία Δημοσίευσης2020-
Θεματική ΚατηγορίαUnsaturated porous mediaen
Θεματική ΚατηγορίαClay colloidsen
Θεματική ΚατηγορίαKaoliniteen
Θεματική ΚατηγορίαMontmorilloniteen
Θεματική ΚατηγορίαFormaldehydeen
Θεματική ΚατηγορίαSanden
Θεματική ΚατηγορίαCo-transporten
Βιβλιογραφική ΑναφοράT. V. Fountouli and C. V. Chrysikopoulos, “Effect of clay colloid particles on formaldehyde transport in unsaturated porous media,” Water, vol. 12, no. 12, Dec. 2020. doi: 10.3390/w12123541en

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