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Characterization and mobility of geogenic chromium in soils and river bed sediments of Asopos basin

Lilli Maria, Moraetis Daniel, Nikolaidis Nikolaos, Karatzas Giorgos, Kalogerakis Nikos

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URIhttp://purl.tuc.gr/dl/dias/7AB76D4B-B5DD-41A2-BA0E-8880E043A62C-
Identifierhttps://doi.org/10.1016/j.jhazmat.2014.07.037-
Languageen-
Extent7en
TitleCharacterization and mobility of geogenic chromium in soils and river bed sediments of Asopos basinen
CreatorLilli Mariaen
CreatorΛιλλη Μαριαel
Creator Moraetis Danielen
CreatorNikolaidis Nikolaosen
CreatorΝικολαιδης Νικολαοςel
CreatorKaratzas Giorgosen
CreatorΚαρατζας Γιωργοςel
CreatorKalogerakis Nikosen
CreatorΚαλογερακης Νικοςel
PublisherElsevieren
DescriptionΔημοσίευση σε επιστημονικό περιοδικό el
Content SummaryA field and laboratory study was conducted to assess the origin and mobility of CrVI in Asopos basin in Greece. Sampling was designed in such way as to capture the spatial variability of chromium occurring in sediments and soils in different lithological units in the area. Physicochemical and geochemical characterization of surface agricultural soils obtained from river terraces and river bed sediments was conducted in order to determine the natural background of chromium. Lithologies with strong calcareous, siliceous and ultramafic components were identified using principal component analysis. Laboratory mobility studies quantified the rates of chromium sorption and release from soils and their capacity to adsorb chromium. Heavy metal analysis and local geology study support the hypothesis that the main source of chromium is of geogenic origin. Chromium distribution in Asopos river bed was influenced from the eroded products derived from extensive areas with ultramafic rocks the last 5 Ma. The mobility studies showed that leaching process was very fast and sorption capacity was significant and capable to retain chromium in case of waste release in the river. Finally the mobility of chromium release is limited due to existing attenuation capacity controlled by ferric oxides coatings on the soil and sediments.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-10-20-
Date of Publication2015-
SubjectHexavalent chromiumen
Subject Geogenic chromiumen
SubjectSoil/sediment characterizationen
Subject Mobilityen
Bibliographic CitationM.A. Lilli , D. Moraetis, N.P. Nikolaidis, G.P. Karatzas, and N. Kalogerakis, "Characterization and mobility of geogenic chromium in soils and river bed sediments of Asopos basin," Journal of Hazardous Materials, vol. 281, pp. 12–19, Jan. 2015. doi: 10.1016/j.jhazmat.2014.07.037en

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