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Thermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA)

Damartzis Theodoros, Vamvouka Despoina, Sfakiotakis Stylianos, Zabaniotou, Anastasia, 1956-

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URIhttp://purl.tuc.gr/dl/dias/E3962468-E24E-4D9D-8468-0B9368D65BB3-
Identifierhttp://www.sciencedirect.com/science/article/pii/S0960852411002458-
Identifierhttps://doi.org/10.1016/j.biortech.2011.02.060-
Languageen-
Extent9 pagesen
TitleThermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA)en
CreatorDamartzis Theodorosen
CreatorVamvouka Despoinaen
CreatorΒαμβουκα Δεσποιναel
CreatorSfakiotakis Stylianosen
CreatorΣφακιωτακης Στυλιανοςel
CreatorZabaniotou, Anastasia, 1956-en
PublisherElsevieren
Content SummaryA key element in the design of sustainable pyrolysis processes is the thermal degradation kinetics of biomass. In this work, pyrolysis tests for cardoon (Cynara carduculus) stems and leaves were performed in a non-isothermal thermogravimetric analyzer (TGA) in order to determine the thermal degradation behavior of both stems and leaves. The kinetic parameters of the process were evaluated using three different kinetic models, the independent parallel reaction model, KAS and OFW iso-conversional model. Good agreement with the experimental TGA data was observed for all models, the best being with the independent parallel reaction model. A variance in the activation energy with conversion was observed when the KAS and OFW models were employed, which reveals that the pyrolysis of cardoon progresses through more complex and multi-step kinetics.en
Type of ItemPeer-Reviewed Journal Publicationen
Type of ItemΔημοσίευση σε Περιοδικό με Κριτέςel
Licensehttp://creativecommons.org/licenses/by/4.0/en
Date of Item2015-10-27-
Date of Publication2011-
SubjectBiomassen
SubjectKinetic studyen
SubjectThermogravimetric analysisen
SubjectPyrolysisen
SubjectCardoonen
Bibliographic CitationTh. Damartzis, D. Vamvuka, S. Sfakiotakis and A. Zabaniotou, “Thermal degradation studies and kinetic modeling of cardoon (Cynara cardunculus) pyrolysis using thermogravimetric analysis (TGA)”, Biores. Technol., vol. 102, no. 10, pp. 6230-6238, May 2011. doi:10.1016/j.biortech.2011.02.060en

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