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Structure-property relationships and stability studies of multi-promoted catalytic systems for nitrogen (NOx) and/or nitrous (N2O) oxides abatement

Pachatouridou Eleni

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URI: http://purl.tuc.gr/dl/dias/00B4886E-21E5-4D58-ACDA-BE0B854E65BB
Year 2017
Type of Item Doctoral Dissertation
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Bibliographic Citation Eleni Pachatouridou, "Structure-property relationships and stability studies of multi-promoted catalytic systems for nitrogen (NOx) and/or nitrous (N2O) oxides abatement", Doctoral Dissertation, School of Production Engineering and Management, Technical University of Crete, Chania, Greece, 2017 https://doi.org/10.26233/heallink.tuc.69056
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Summary

The current thesis aims at exploring the impact of structural (CeO2, La2O3) and surface (K) promoters on the solid state properties and the surface chemistry of Al2O3-based noble metal (Pt, Pd, Ir) catalysts, during nitro-gen (NOx) and/or nitrous (N2O) oxides abatement. Various characterization techniques, such as N2 physisorp-tion (BET method), X-ray diffraction (XRD), Temperature programmed methods (TPR/TPD), microscopy meth-ods (HRTEM, STEM) and infrared spectroscopy (FTIR, DRIFTS) were employed to gain insight into the impact of structural/surface promoters on the physicochemical characteristics, as well as on the activity and stability performance of the as-prepared catalysts. In any case, particular emphasis was devoted in the present thesis on the underlying mechanism of promoters and the establishment of structure-property relationships.

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