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Highly active and stable TiO2-supported Au nanoparticles for CO2 reduction

Kyriakou Vasileios, Vourros A., Garagounis Ioannis, Carabineiro, Sónia Alexandra Correia, Maldonado-Hódar, Francisco Jose, Marnellos, Georges E, Konsolakis Michail

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URI: http://purl.tuc.gr/dl/dias/1DC6BE36-7F2B-42DA-AFA6-B9C7DDC9FD99
Year 2017
Type of Item Peer-Reviewed Journal Publication
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Bibliographic Citation V. Kyriakou, A. Vourros, I. Garagounis, S. A. C. Carabineiro, F. J. Maldonado-Hódar, G. E. Marnellos and M. Konsolakis, "Highly active and stable TiO2-supported Au nanoparticles for CO2 reduction," Catal. Commun., vol. 98, pp. 52-56, Jul. 2017. doi: 10.1016/j.catcom.2017.05.003 https://doi.org/10.1016/j.catcom.2017.05.003
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Summary

Au nanoparticles (2.2 nm) deposited on TiO2 by the deposition-precipitation method were found to be extremely active and stable for CO2 hydrogenation to CO. A CO2 to CO yield up to 50% was achieved at temperatures as low as 400 °C for at least 60 h. Under identical reaction conditions, both bare TiO2 and Au/Al2O3 were practically inactive for CO2 reduction. The unique combination of the Au nanoparticles and TiO2 support – linked to a peculiar synergistic effect – is essential to the enhanced CO2 reduction activity.

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