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Identification of iron corrosion products in arsenic remediation using zero valent iron

Nikolaidis Nikolaos, Tyrovola Konstantina, J.J. Ojeda, M.E. Romero-Gonzalez, S.A. Banwart

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URI: http://purl.tuc.gr/dl/dias/7DAAFC84-45AB-486E-8FD7-6D4394607468
Year 2008
Type of Item Conference Full Paper
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Bibliographic Citation K. Tyrovola, N.P. Nikolaidis, J.J. Ojeda, M.E. Romero-Gonzalez, and S.A. Banwart. (2088, October). Identification of iron corrosion products in arsenic remediation using zero valent iron. Presented at 1st International Conference "Hazardous Waste Management". [Online]. Available: http://www.srcosmos.gr/srcosmos/showpub.aspx?aa=13198
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Summary

The objective of this study was to identify the corrosion products which areformed onto the surface of Zero Valent Iron (ZVI) during arsenic removal from geothermalgroundwaters and to clarify the role of the corrosion products in the mechanism of arsenicremoval. The results of this study demonstrated that carbonate green rust was formed onto thesurface of ZVI during short and long term column experiments. In addition, As(V) was mainlyreduced to As(III) onto the surface of ZVI. A small amount of As(III) was oxidized to As(V) andthat was attributed to the formation of carbonate green rust and other corrosion products on thesurface of ZVI.

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