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Translational invariance in the theory of nucleation

Lazaridis Michalis, Kevrekidis, Panayotis G, Drossinos, Ioannis, Georgopoulos,P.G

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URI: http://purl.tuc.gr/dl/dias/9840620C-DBEF-4C4A-B79A-F37C7A5447E5
Year 2000
Type of Item Conference Full Paper
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Bibliographic Citation P. Kevrekidis, Y. Drossinos, M. Lazaridis , P. G. Georgopoulos,"Translational invariance in the theory of nucleation," in 200 15th Int. Conf. on Nucleation and Atm. Aerosols,doi: 10.1063/1.1361850 https://doi.org/10.1063/1.1361850
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Summary

A connection between field-theoretic descriptions of condensation and density-functional theories of nucleation is established. The time-independent differential equation for the density profile of a liquid droplet that mediates the transition from liquid to gas phase is derived based on a variational principle. The droplet profile depends crucially on an attractive interaction term. A physically motivated form for the one-dimensional droplet profile is postulated, the droplet translational eigenmode for an infinite system is identified, and its contribution to the nucleation-rate prefactor is evaluated.

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